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Latest News: Permanganate 101 Webinar: What You Need to Know
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Aerial view of a vibrant green and yellow lake surrounded by barren, leafless trees and a gray, barren landscape. The colors create a striking and contrasting natural scene.

Cyanide Destruction

The Hazard of Cyanide in Gold Recovery

Cyanide is a cornerstone of gold leaching processes, enabling efficient gold recovery from ore. However, its toxic nature presents critical environmental and safety challenges. Improper handling or disposal of cyanide can lead to severe environmental contamination, harm to local communities, and regulatory penalties. Moreover, residual cyanide in process water and tailings requires careful management to mitigate risks associated with accidental spills, toxic releases, and long-term environmental impact.

How Carus Can Help

Carus offers innovative permanganate solutions to neutralize cyanide safely and effectively, reducing its environmental footprint while supporting efficient gold leaching operations:

Eco-Friendly Oxidation:

Using CARUSOL® liquid permanganate, CAIROX® potassium permanganate, or AQUOX® potassium permanganate (Carus Europe Only), cyanide is rapidly oxidized into non-toxic byproducts, such as carbonates and nitrogen gas, making disposal safe and environmentally responsible.

Regulatory Compliance:

Our solutions align with stringent environmental standards, ensuring safe cyanide destruction and supporting compliance with local, national, and international regulations.

Consistent, Reliable Performance:

Carus permanganate products are engineered to provide dependable performance under varying site conditions, including challenging water chemistry and temperature variations.

Operational Flexibility:

Permanganate solutions integrate seamlessly into existing cyanide treatment systems, requiring minimal modifications to current processes.

Benefits in Action

Enhanced Safety:

Reduce the risks of toxic exposure for workers and surrounding communities.

Regulatory Confidence:

Demonstrate commitment to meeting or exceeding regulatory compliance for cyanide management.

Environmental Stewardship:

Achieve sustainable gold recovery by minimizing environmental contamination and safeguarding ecosystems.

Cost-Effective Sustainability:

Minimize long-term liability and treatment costs with efficient and reliable permanganate-based detoxification processes.

Solutions in Practice

Carus permanganates are versatile and effective in various gold mining applications, including:

  • Treating cyanide-laden tailings before disposal.
  • Detoxifying cyanide in process water for recycling or safe discharge.
  • Supporting emergency spill response with rapid cyanide neutralization.

Resources

  • Product Data Sheets
  • Case Studies

Frequently Asked Questions


What is potassium permanganate & sodium (liquid) permanganate?

Permanganate is a chemical compound composed of manganese and oxygen. The chemical formulas for potassium permanganate and sodium permanganate are KMnO₄ and NaMnO₄, respectively. When dissolved in water, permanganate ions give the water a distinctive purple color, which can range from light pink to deep purple depending on their concentration.

Permanganate is known for its strong oxidizing properties, which means it can react with a wide variety of organic and inorganic compounds. This makes it highly effective in water treatment processes for the breakdown, neutralization, and removal of metals and other chemical contaminants.

How does our CAIROX® potassium permanganate or CARUSOL® liquid permanganate clean water?

In mining operations, water becomes polluted with various chemicals and metals that are harmful to the environment if not properly treated. Our CAIROX or CARUSOL permanganate products act as oxidants in water treatment, meaning they facilitate the transfer of electrons from harmful substances to themselves. This process, known as oxidation, breaks down organic matter and oxidizes dissolved metals to convert the toxic substances into less harmful forms. Physical treatment processes such as clarification and filtration can then be used to remove the oxidized contaminants.

Oxidation mechanism

The oxidation process with CAIROX or CARUSOL typically involves the transfer of oxygen atoms to the contaminant molecules. Permanganate ions (MnO₄⁻) react with organic and inorganic pollutants by breaking their chemical bonds, thereby degrading them into simpler, less toxic compounds. For example, in the case of cyanide contamination from mining activities, CAIROX or CARUSOL liquid permanganate can oxidize cyanide ions (CN⁻) into less harmful substances like cyanate (OCN-), ammonium (NH4 +), nitrogen gas (N₂) and carbon dioxide (CO₂).

The by-products of permanganate oxidation reactions are hydrous manganese oxides, which can act as effective coagulant and adsorption aids, helping to remove other impurities (e.g., positively charged ions, organics, hydrogen sulfide) and reduce or eliminate the usage of other treatment chemicals.

Where is CAIROX® potassium permanganate or CARUSOL® liquid permanganate used?
  1. Mining Industry: The mining industry generates large volumes of wastewater containing heavy metals, metal cyanides, and other contaminants. These pollutants can severely impact local ecosystems if released untreated. CAIROX potassium permanganate or CARUSOL liquid permanganate are employed in mining wastewater treatment plants to effectively neutralize cyanide compounds and oxidize heavy metals such as iron, manganese, arsenic, and thallium. By facilitating the breakdown of these pollutants, our permanganate products help ensure that discharged water meets environmental standards and poses minimal risk to aquatic life.
  2. Industrial Applications: Beyond mining, CAIROX and CARUSOL find applications in various industrial sectors where wastewater contains organic pollutants, oils, sulfur- containing compounds (e.g., H2S) or metals. Industries such as chemical manufacturing, food and beverage production, metal processing and plating, soil remediation, and textile production utilize permanganate for wastewater treatment to comply with environmental regulations and minimize their ecological footprint.
Safety considerations
  • Dosage Control: Proper dosing of CAIROX and CARUSOL is critical to optimizing treatment performance and cost, and to prevent overdosing, which can result in residual permanganate in treated water.
  • Environmental Impact: Residual concentrations of CAIROX or CARUSOL must be monitored to ensure they comply with regulatory standards before discharged water re-enters natural ecosystems.
  • Health Concerns: Direct exposure to permanganate can irritate the skin, eyes, and respiratory tract. Therefore, personal protective equipment (PPE) and safety protocols are essential during handling and application.
Benefits of using CAIROX® potassium permanganate or CARUSOL® liquid permanganate in wastewater treatment
  • Efficiency: CAIROX potassium permanganate and CARUSOL liquid permanganate are highly effective in treating a wide range of contaminants due to their strong oxidizing properties. They can also improve performance and reduce required maintenance of downstream treatment processes (e.g., filtration systems).
  • Versatility: They can target both organic and inorganic pollutants, making it suitable for diverse industrial wastewater treatment applications.
  • Safety: When used correctly and in controlled amounts, CAIROX and CARUSOL are considered safe chemicals for water treatment processes. Proper monitoring and dosing ensure that their impact on the environment is minimized.
  • Cost-Effectiveness: Despite being a potent oxidizing agent, CAIROX and CARUSOL are relatively affordable compared to some other alternative treatment methods. Its efficiency in breaking down contaminants translates to lower operational costs and reduced environmental impact over time.
How safe are CAIROX® potassium permanganate & CARUSOL® liquid permanganate?

CAIROX and CARUSOL are powerful chemicals that must be handled with care to ensure safety for both operators and the environment. While they are effective in treating wastewater, improper handling or excessive use can lead to unintended consequences. Carus can help address any safety concerns as part of our extensive on-site technical assistance for chemical application and product safety training.

Achieve Safe and Sustainable Gold Recovery

Contact Carus today to learn how our permanganate solutions can streamline cyanide detoxification in your gold leaching operations.

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